tuneup utilities 2008 there is a part of that program called tuneup shredder which uses a method developed by the US Department of Defence (DoD 5220.2-m)
Before being deleted, the files are overwritten several times with certain data patterns, thus nullifying the original content so that even expensive examinations of the magnetic structure of the drive in special laboratories cannot lead to data recovery.
there is one downside this is not a free program.
i use this program and it is briliant
http://www.tuneup-software.co.uk/services/privacy/