Open the computer and remove the IDE cable from both drives (remember which is connected to which: grey/middle/slave > black/end/Master) and reboot once without either drive connected.
Then shut down again and go back and connect the Master by itself and boot again. If XP detects it and loads the drivers then shutdown again and try the slave as well.
If this does not work please let us know exactly what happens as to each step.
If you are unfamiliar working inside computers you might want to read this on static damage:
ESD - What can I do to avoid damage
You might as well also unplug and replug that IDE cable into the motherboard to insure a good connection. Also another check if the above fails is to verify that the BIOS detects these drives.